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National Industrial Research Institute of Nagoya(NIRIN), Japan


1. Project Name
 2. Duration
 3. Research Category 1
 4. Research Category 2
 5. Research Field
 6. Researchers
 7. Affiliation 1
 8. Affiliation 2
 9. Address
10. Country
11. Phone
12. Fax
13. Project Summary
14. Publications
15. International Joint Study with


1 Studies of Development of Biological Purification Systems Using Non-Reused 
  Local Materials for the Improvement of Water Environment 
2 1994-1996
3 water, wastes
4 biological purification system
5 engineering, chemistry
6 Motohiro TORIYAMA, Yoshiyuki YOKOGAWA, Yukari KAWAMOTO, 
  Kaori NISHIZAWA, Fukue NAGATA, Hajime NAGAE,
7 Engineering Ceramcs Lab., Ceramic Science Dept.,
  Bioceramics Lab., Manufacturing Technology Lab, Ceramic Technology Dept.,
8 NIRIN, AIST, MITI
9 1-1 Hirate-cho, Kita-ku, Nagoya, Aichi 462-8510 
10 Japan
11 81-52-911-2111
12 81-52-916-6993
13 This study aims at developing in situ water treatment systems employing 
   recycled local materials for use in rivers and lakes . Waste ceramic materials
   have been considered potentially useful as recycling materials for preparation
   of porous carriers supporting microbial adhesion and growth. Effective 
   microorganisms, including aerobes and anaerobes, used in the purification of 
   water supplies are immobilized in the surface-modified porous ceramics by 
   immersing the ceramics into a seed culture broth. Design and synthesis methods
   for porous ceramics carriers with enhanced microbial functions from recyclable
   waste materials are investigated. 
14 1) Kaori Nishizawa, Takahiro Suzuki, Motohiro Toriyama, Yoshiyuki Yokogawwa, 
      Yukari Kawamoto, Fukue Nagata, Michael Roger Mucalo, Tetsuya Kameyama, 
      Surface Modification of Bioceramics and the Effects of their Surface 
      Characteristics on the Adhesion of Anchorage-Dependent Animal Cells, 
      Proceedings of First International Conferenced on Adhesion Science, 1995. 
   2) Takahiro Suzuki, Kaori Nishizawa, Yoshiyuki Yokogawa, Fukue Nagata, 
      Yukari Kawamoto, and Tetsuya Kameyama, Time-Dependent Variation of the 
      Surface Structure of Bioceramics in Tissue Culture Medium and the Effect 
      on Adhesiveness of Cells, J.Fermentation and Bioengineering, 81, 226-233,
      1996
   3) Kaori Nishizawa et.al., Effects of the Surface Wettability and Zeta 
      Potential of Calcium Phosphate Bioceramics on the Adhesion and Growth of 
      Anchorage-Dependent Animal Cells, Reports of the National Industrial 
      Research Institute of Nagoya, 44, 8-14, 1995 
15


1 A study of the development of high-temperature CO2 separator 
2 1996-1998
3 global warming
4 adsorption,separation
5 engineering,chemistry
6 Kenzi SUZUKI,Masakazu HORIO,Hiroyuki MASUDA, Toyohiko SUGIYAMA,
  Tatsuro HORIUCHI,Tosihiko OSAKI 
7 Ecoceramics Lab, Ceramics Technology Dept. 
8 NIRIN,AIST,MITI
9 1-1 Hirate-cho, Kita-ku, Nagoya, Aichi 462-8510 
10 Japan
11 81-52-911-2111
12 81-52-916-6993
13 The conservation and improvement of the global environment is becoming an 
   extremely issue. R&D studies on separation and enrichment films of CO2 
   (the main contributing greenhouse gas to global warming) from high-temperature
   exhaust gas are carried out using ceramics such as MgO,CaO,Al2O3,Sepiolite,
   Dolomite,rare earth oxides etc. The development of long-life and highly 
   efficient catalysts to reduce the collected CO2 to useful synthetic gases 
   (e.g., CO and H2) is also being studied using the PSRA (Pulse Surface Reaction
    Rate Analysis) method. 
14 1) Masakazu Horio et al.,Characteristics of Clay Materials for the Separation 
      of Carbon Dioxide from N2-CO2 Mixture by Gas Chromatography,Nippon 
      Kagaku-kaishi,1995,83-85. 
   2) Masakazu Horio et al., Characteristics of Sepiolite for the Separation of 
      Carbon Dioxide from N2-CO2 Mixture,Nippon Kagaku-kaishi,1995,273-276. 
   3) Kenzi Suzuki et al.,Separation of CO2 and N2 Using Sepiolite,Proc.Inter.
      Symp.Envir.Issues Ceram.,Oct 19 and 20,1994,175-180.
15


1  Study on acid rain in east Asia
2  1996-2000
3  Air, Water
4  Monitoring
5  Chemistry
6  Kazuhiko TANAKA, Kazutoku OHTA, Masamichi FURUKAWA, Tooru SHIMIZU
7  Analytical Chemistry Lab. Department of Chemistry
8  NIRIN, AIST, MITI
9  1-1,Hirate-cho, Kita-ku, Nagoya, Aichi 462-8510 
10 Japan
11 81-52-911-2111
12 81-52-916-2802
13 The purpose of this joint reearch is to establish an automatic monitoring 
   system for measuring the global environmental pollutants such as acid rain 
   components in east-Asia region.  The main research activities to be performed 
   at the NIRIN, University of Tasmania(Australia), Texas Texh University(USA), 
   Chungbuk National University(Korea) are the development of acid rain 
   monitoring network system consisting of the ion chromatograph for monitoring 
   the acid rain components including sulfate, nitrate, chloride, bicarbonate
   (alkalinity), sodium, ammonium, potassium, magnesium, and calcium ions in 
   rain and environmental waters and the meteorological analyzer with a satellite.
14 1) K.Tanaka et al.,Ion-exclusion chromatography with conductimetric detection 
      of aliphatic carboxylic acids on an H{-form cation-exchange resin by 
      elution with polyols and  sugars,J.Chromatogr.A,706,385-393,1995. 
   2) K.Tanaka, P.R.Haddad, 
      Acid rain monitoring by ion- exclusion/cation-exchange chromatography, 
      Trends in Anal. Chem.,in press. 3)K.Ohta et al.,Non-suppressed ion 
      chromatography of inorganic anions, magnesium and calcium ions using 
      apyromellitate eluent and its application in evaluating environmental 
      water quality, J.Chromatogr.A,in print.
15 University of Tasmania(Australia), Texas Tech University(USA), 
   Chungbuk National University(Korea)  


1 Studies on the Molecular Design of High Performance Halon Replacements and 
  the Fundamental evaluation as a fire-extinguisher. 
2 1996-1998
3 global change
4 counter measures
5 chemistry
6 Takashi ABE, Eiji HAYASHI, Taizo ONO, Vadim A. SOLOSHONOK, Masakazu NISHIDA, 
  Haruhiko Fukaya, Yoshio HAYAKAWA
7 Fluorine Chemistry Lab., Chemistry Dept., 
8 NIRIN,AIST, MITI
9 1-1 Hirate-cho, Kita-ku, Nagoya 462-8510
10 Japan
11 81-52-911-2111
12 81-52-916-2802
13 The aim of this study is to develop the bromine-free halon replacements which 
   have a comparative fire-extinguishing ability with that of Halons. Halons have
    a bromine atom for imparting the good fire extinguishing ability in the 
   molecule, but their use was banned due to the reason for the destruction of 
   the ozone layer by the bromine. The key point of our work is the use of CF3 
   radical in place of a bromine atom as a function of fire-extinguishing 
   mechanism in halon replacements. This project consists of the molecular 
   design of new Halon replacemnts of which molecular structure can genarate 
   CF3 radical effectively on contace with fire and the evaluation as a 
   fire-extinguisher.
14 1) Haruhiko Fukaya et al., Synthesis and Evaluation of Perfluoroamines as 
      Halon Alternatives, Environmenta Chemistry, 3, 271-277, 1993. 
   2) Haruhiko Fukaya et al., New Fire Suppression Mechanism of 
      Perfluoroalkylamines, J.Chem.Soc.,Chem. Commn., 1995, 1207-1208. 
   3) Kazuo Takahashi et al., Inhibition of Cobustion by Bromine-Free 
      Polyfluorocarbons. 1. Burning Velocities of Methane Flames Containing 
      Polyfluoroalkylamines, Combustion Science and Technology, 102, 213-230,
      1994.
15


1 Studies on Plant Growth Regulators for Useful Plants 
2 1996-1999
3 energy, food problem, global warming
4 organic synthesis, plant growth regulators 
5 organic chemistry, sythetic chemistry
6 Masato KATAYMA, Hiroshi KIMOTO, Shozo FUJII, Katsuya KATO 
7 Lab. of Bioorganic Chemistry ,
  Dept. of Chemistry, Director of Dept. of Chemistry 
8 NIRIN, AIST, MITI
9 1-1 Hirate-cho, Kita-ku, Nagoya, Aichi 462-8510 
10 Japan
11 81-52 911-2111
12 81-52-914-3439
13 The objective of this study is to develop novel plant growth regulators(PGRs) 
   for increasing the tapioca production yield and for stimulating the growth of 
   important plants with high CO2 fixation ability.  Fluorinated and chlorinated 
   plant growrh regulators have been synthesized. It is found in the joint 
   project with the Thai Tapioca Development Institute that both of the PGRs 
   stimulated remarkably the tuber growth of tapioca. The chlorinated and 
   fluorinated PGRs are useful for the preparation of saplings and the 
   stimulation of the growth of many plants which should play an important role 
   for the improvement of global environment. 
14 1) Masato Katayama et al.,
      (S)-(+)-4,4,4-Trifluoroindole-3-(indole-3-)butyric Acid, a Novel 
      Fluorinated Plant Growth Regulator, Experientia, 51, 721-724,1995. 
   2) Masato Katayama and Rakesh K. Gautam, Synthesis and Biological Activities 
      of Substituted 4,4,4-Trifluoro-3-(indole-3-)butyric Acids, Novel 
      Fluorinated Plant Growth Regulators, Biosci.Biotech.Biochem., 60, 755-759,
      1996. 
   3) Katsuya Kato et al.,
      Optical Resolution of 2,2,2-Trifluoro-1-(9-Phenanthryl)ethanol via 
      Enzymatic Alcohols of Its Activated Ester, J.Ferment.Bioeng., 81, 206-211, 
      1996.
15 The Thai Tapioca Development Institute (Thailand) 


1 Study on Environmental Purification Technology Using Ceramics Photocatalyst
2 1995-1998
3 water, wastes, hazardous substances
4 reaction mechanism and purification
5 engineering
6 Hiroshi TAODA, Eiji WATANABE, Kazumi KATO, Kozo ISEDA
7 Ecomaterial Lab., Multi-functional Material Science Dept.
8 NIRIN, AIST, MITI
9 1-1 Hirate-cho, Kita-ku, Nagoya 462-8510
10 Japan
11 81-52-911-2111
12 81-52-916-2802
13 Recently, pollution of valuable water due to daily waste water or industrial 
   waste water has been spreading on the earthwide scale to become a world wide 
   problem. The treatment of waste water using TiO2 photocatalyst is able to 
   decompose toxic and bioresistant organic pollutants readily. In such water 
   treatment studies, TiO2 powders in general have been utilized as 
   photocatalyst. TiO2 film photocatalysts have several advantages:
   1)it is easy to treat, 
   2)filtration is not necessary to separate catalysts from treated water, 
   3)continuous treatment of waste water is possible. In this study, 
   the development of highly active TiO2 film photocatalysts prepared by sol-gel 
   method, the research on the destruction of bioresistant organic pollutants and
   the development of water treatment system using the TiO2 film photocatalysts 
   are being performed.
14 Hiroshi Taoda, Eiji Watanabe and Kazumi Kato, Photocatalytic Treatment of 
   Organochlorine Compounds Using Catalyst Films, J.Water and Waste, 38,
   290-296, 1996
15